Schirmer, Mario

2009, Balcke, Gerd Ulrich, Paschke, Heidrun, Vogt, Carsten, Schirmer, Mario

Chlorobenzene-contaminated groundwater was used to assess pulsed gas sparging as a minimum effort aeration strategy to enhance intrinsic natural attenuation. In contrast to existing biosparging operations, oxygen was supplied at minimum rate by reducing the gas injection frequency to 0.33 day(-1). Field tests in a model aquifer were conducted in a 12 m long reactor, filled with indigenous aquifer material and continuously recharged with polluted groundwater over 3 years. The closed arrangement allowed yield balances, cost accounting as well as the investigation of spatial distributions of parameters which are sensitive to the biodegradation process. Depending on the injection frequency and on the gas chosen for injection (pure oxygen or air) oxygen-deficient conditions prevailed in the aquifer. Despite the limiting availability of dissolved oxygen in the groundwater, chlorobenzene degradation under oxygen-deficient conditions proved to be more effective than under conditions with dissolved oxygen being available in high concentrations. (C) 2009 Elsevier Ltd. All rights reserved.

2003, Schirmer, Mario, Butler, Barbara J, Church, Clinton D, Barker, James F, Nadarajah, Nalina

Mainly due to intrinsic biodegradation, monitored natural attenuation can be an effective and inexpensive remediation strategy at petroleum release sites. However, gasoline additives such as methyl tert-butyl ether (MTBE) can jeopardize this strategy because these compounds often degrade, if at all, at a slower rate than the collectively benzene, toluene, ethylbenzene and the xylene (BTEX) compounds. Investigation of whether a compound degrades under certain conditions, and at what rate, is therefore important to the assessment of the intrinsic remediation potential of aquifers. A natural gradient experiment with dissolved MTBE-containing gasoline in the shallow, aerobic sand aquifer at Canadian Forces Base (CFB) Borden (Ontario, Canada) from 1988 to 1996 suggested that biodegradation was the main cause of attenuation for MTBE within the aquifer. This laboratory study demonstrates biologically catalyzed MTBE degradation in Borden aquifer-like environments, and so supports the idea that attenuation due to biodegradation may have occurred in the natural gradient experiment. In an experiment with batch microcosms of aquifer material, three of the microcosms ultimately degraded MTBE to below detection, although this required more than 189 days (or >300 days in one case). Failure to detect the daughter product tert-butyl alcohol (TBA) in the field and the batch experiments could be because TBA was more readily degradable than MTBE under Borden conditions. (C) 2002 Elsevier Science B.V. All rights reserved.

1999, Schirmer, Mario, Butler, Barbara J, Roy, James W, Frind, Emil O, Barker, James F

An analysis of aerobic m-xylene biodegradation kinetics was performed on the results of laboratory batch microcosms. A modified version of the computer model BIO3D was used to determine the Monod kinetic parameters, k(max) (maximum utilization rate) and K-S (half-utilization constant), as well as the Haldane inhibition concentration, K-I, for pristine Borden aquifer material, The proposed method allows for substrate degradation under microbial growth conditions. The problem of non-uniqueness of the calculated parameters was overcome by using several different initial substrate concentrations. With a relative-least-squares technique, unique kinetic degradation parameters were obtained. Calculation of the microbial yield, Y, based on microbial counts from the beginning and the end of the experiments was crucial for reducing the number of unknowns in the system and therefore for the accurate determination of the kinetic degradation parameters, The kinetic parameters obtained in the present study were found to agree well with values reported in the literature. (C) 1999 Elsevier Science B.V. All rights reserved.