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  • Publication
    Métadonnées seulement
    A deterministic approach to the coupled analysis of karst springs' hydrographs and chemographs
    (2003)
    Grasso, D Alessandro
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    During the chemically based recession flow phase of karstic springs the carbonate (dissolved limestone) concentration can be expressed as negative power of the flow rate. The empirically determined Conc/Q relationship allows two parameters (alpha and A) to be defined, of which one (alpha) depends on the geometric dimensions of the saturated (submerged) karstic network. In this paper we present a deterministic model which simulates the concentration of carbonate at the outlet of a network of circular rectilinear conduits as a function of flow rate. This model, based on hydraulic principles and the calcite dissolution kinetics, allows the sensitivity of the alpha and A parameters to be studied under different chemical, physical and geometric scenarios. Simulation results show that A is a function of the calcite saturation concentration, whereas alpha depends on the spatial dimensions of the karstic network (void length and aperture). The deterministic model results were applied to real karstic systems to evaluate the geometric dimensions of submerged karstic networks. (C) 2002 Elsevier Science B.V. All rights reserved.
  • Publication
    Métadonnées seulement
    Epikarst storage in a karst aquifer: a conceptual model based on isotopic data, Milandre test site, Switzerland
    (2003)
    Perrin, Jérôme
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    The Milandre test site is a karst aquifer characterized by diffuse infiltration, a well developed conduit network, and several tributaries feeding an underground river. Field data include discharge rate measurements, stable isotopes, weekly rainfall and spring-water isotope sampling, and detailed isotope sampling during three flood events. Flood sampling was carried out at several tributaries corresponding to conduit flow, vadose flow and seepage flow. Weekly sampling showed a strong buffering of the rainfall isotopic signal at the spring. This attenuation suggests an important mixing reservoir in the system. Flood events showed highly peaking hydraulic responses but buffered rain isotope responses. These results indicate that the soil and epikarst sub-systems have an important storage capacity. A conceptual model of flow and transport in the soil and epikarst zone is proposed: Soil plays an important role in mixing due to the presence of capillary water storage. Consequently dampened concentrations reach the epikarst despite a rapid hydraulic response. The epikarst acts as the storage element and distributes water as either a base flow component or a quick flow component. When recharge exceeds a given threshold, excess infiltrated water bypasses the soil and epikarst and reaches the saturated zone as fresh flow. Based on this model, the significance of phreatic storage is thought to be limited, at least in Milandre test site. Hence the saturated zone is seen mainly as a transmissive zone through its well developed conduit network. (C) 2003 Elsevier B.V. All rights reserved.