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Aluminous granulites from the Pulur complex, NE Turkey : a case of partial melting, efficient melt extraction and crystallisation

2004, Topuz, Gültekin, Altherr, Rainer, Kalt, Angelika, Satır, Muharrem, Werner, Olaf, Schwarz, Winfried H.

In the Pulur complex, NE Turkey, a heterogeneous rock sequence ranging from quartz-rich mesocratic gneisses to silica- and alkali-deficient, Fe-, Mg- and Al-rich melanocratic rocks is characterized by granulite-facies assemblages involving garnet, cordierite, sillimanite, ilmenite, ±spinel, ±plagioclase, ±quartz, ±biotite, ±corundum, rutile and monazite. Textural evidence for partial melting in the aluminous granulites, particularly leucosomes, is largely absent or strongly obliterated by a late-stage hydrothermal overprint. However, inclusion relations, high peak P–T conditions, the refractory modes, bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting. The melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica-rich, bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with SiO2. Peak conditions are estimated to be ≥800 °C and 0.7–0.8 GPa. Subsequent near-isothermal decompression to ~0.4–0.5 GPa at 800–730 °C is suggested by the formation of cordierite coronas and cordierite–spinel symplectites around garnet and in the matrix. Sm–Nd, Rb–Sr and 40Ar/39Ar isotope data indicate peak conditions at ~330 Ma and cooling below 300 °C at ~310 Ma.

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Nd, Sr, and Pb isotopic evidence for diverse lithospheric mantle sources of East African Rift carbonatites

1997-09-15, Kalt, Angelika, Hegner, E., Satır, Muharrem

Carbonatites may provide valuable information on mantle source compositions as their isotopic ratios are insensitive to crustal contamination. In order to place constraints on mantle sources, nineteen samples from three Miocene to Quaternary carbonatite areas in the East African Rift were analysed for their Sr, Nd, and Pb isotopic compositions. The samples from Kerimasi (northern Tanzania), Homa Mountain, and Wasaki Peninsula (both Lake Victoria, Kenya) as a whole show considerable variations in their isotope ratios (0.70327–0.70502 for 87Sr/86Sr, 0.51249–0.51283 for 143Nd/144Nd, 18.72–20.41 for 206Pb/204Pb, 15.52–15.78 for 207Pb/204Pb, and 39.22–40.47 for 208Pb/204Pb) that lie between the inferred compositions for HIMU (high 238U/204Pb mantle) and EM I (enriched mantle I) components in most isotope plots. The internal isotopic variations of the three carbonatite areas define distinct arrays and diverse trends in isotope diagrams. Although the isotope data define linear arrays in Sr---Nd and Pb---Pb diagrams, which suggest binary mixing between HIMU and EM I mantle components, neither the isotopic compositions of the carbonatites as a whole nor the compositional ranges for individual carbonatite occurrences can be explained by such a process. This clearly emerges from the absence of linear data trends in Sr---Pb and Nd---Pb isotope plots and from the lack of consistent endmember compositions. These features are also displayed by previously published isotope data for East African carbonatites. It is therefore suggested that carbonatite complexes within the East African Rift have isotopically distinct and small mantle sources that are probably not adequately described in terms of the mantle components defined for oceanic basalts. Most likely, these sources are located in a heterogeneous lithospheric mantle and were produced by enrichment and depletion processes at different times and degrees.