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Enrichment of redox-sensitive trace metals (U, V, Mo, As) associated with the late Hauterivian Faraoni oceanic anoxic event

2007, Bodin, Stéphane, Godet, Alexis, Matera, Virginie, Steinmann, Philipp, Vermeulen, Jean, Gardin, Silvia, Adatte, Thierry, Coccioni, Rodolfo, Föllmi, Karl B.

The Faraoni Level is a short-lived oxygen-deficient event that took place during the latest Hauterivian. In order to improve our understanding of the palaeoenvironmental conditions that occurred during this event, we have analysed the contents of several redox-sensitive trace elements (U, V, Mo, As, Co, Cd, Cu, Zn, Ni, Pb, Cr) from bulk limestone samples of late Hauterivian–early Barremian age from three reference sections. U, V, Mo and As show consistent and significant enrichments during the Faraoni event whereas the other redox-sensitive trace elements analysed here are not systematically enriched. In order to explain this discrepant behaviour, we propose that the Faraoni Level was deposited during a period of anoxic conditions near the sediment–water interface. The distinctive peaks in U, V, Mo and As contents are traceable throughout the three studied sections and represent a good correlation tool which helps to identify the Faraoni Level and its equivalents in the western Tethyan realm and outside of the Tethys. For example, a peak in U contents in upper Hauterivian sediments of the northwestern Pacific realm (ODP leg 185, site 1149) may well be an expression of the Faraoni event in this particular basin.

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Evolution of the marine stable carbon-isotope record during the early Cretaceous : A focus on the late Hauterivian and Barremian in the Tethyan realm

2006-02-28, Godet, Alexis, Bodin, Stéphane, Föllmi, Karl B., Vermeulen, Jean, Gardin, Silvia, Fiet, Nicolas, Adatte, Thierry, Berner, Zsolt, Stüben, Doris, Van de Schootbrugge, Bas

In order to improve our understanding of the relationships between the late Hauterivian oceanic anoxic Faraoni event, contemporaneous platform drowning along the northern Tethyan margin and global environmental change in general, we established high-resolution δ13C and δ18O curves for the late Hauterivian and the entire Barremian stage. These data were obtained from whole-rock carbonate samples from the Veveyse de Châtel-Saint-Denis section (Switzerland), the Fiume-Bosso section and the nearby Gorgo a Cerbara section (central Italy), and the Angles section (Barremian stratotype, France). We observe an increase of 0.3‰ in mean δ13C values within sediments from the middle Hauterivian Subsaynella sayni ammonite zone to the Hauterivian–Barremian boundary; δ13C values remain essentially stable during the early Barremian. During the latest early Barremian and most of the late Barremian, δ13C values increase slowly (until the Imerites giraudi zone) and the latest Barremian is characterized by a negative trend in δ13C values, with minimal values at the Barremian–Aptian boundary. During the earliest Aptian, δ13C mean values start to rise again and attain + 2.25‰. We interpret the evolution of the δ13C record as resulting from the interaction between changes in the carbon cycle in the Tethyan basin and the adjacent platforms and continents. In particular, changes towards warmer and more humid conditions on the continent and coeval phases of platform drowning along the northern Tethyan margin may have contributed to enhance the oceanic dissolved inorganic carbon (DIC) reservoir which may have pushed the δ13C record towards more negative values and exerted a general attenuation on the δ13C record. From this may have come the general change from a heterozoan to a photozoan carbonate platform community, which influenced the evolution in δ13C values by increasing the export of aragonite and diminishing export of dissolved organic carbon into the basins.