Options
Süss-Fink, Georg
Nom
Süss-Fink, Georg
Affiliation principale
Fonction
Professeur ordinaire
Email
georg.suess-fink@unine.ch
Identifiants
Résultat de la recherche
11 Résultats
Voici les éléments 1 - 10 sur 11
- PublicationMétadonnées seulementHeteronuclear complexes containing the N,N'-di(2-pyridyl)amidocarboxylferrocene ligand(2012)
; The ferrocene-derived ligand (NC5H4)2NOC-C5H4FeC5H5 reacts with arene ruthenium complexes [(?6-arene)RuCl2]2 to give the cationic complexes [(?6-p-iPrC6H4Me)RuCl{(NC5H4)2NOC-C5H4FeC5H5}]+ (1) and [(?6-C6Me6)RuCl{(NC5H4)2NOC-C5H4FeC5H5}]+ (2), isolated as the hexafluorophosphate and tetrafluoroborate salts, resp., while the reaction with K2PtCl4 yields the neutral complex PtCl2{(NC5H4)2NOC-C5H4FeC5H5} (3). The mol. structures of 2 and 3 were confirmed by single-crystal x-ray diffraction. [on SciFinder(R)] - PublicationMétadonnées seulementDichlorido[1-(2-chloroethyl)-3-(pyridin-4-ylmethyl-?N)urea](?6-hexamethylbenzene)ruthenium(II) chloroform monosolvate(2011)
; The RuII atom in the title compd., [RuCl2(C12H18)(C9H12ClN3O)]·CHCl3, exhibits a typical piano-stool coordination, defined by a hexamethylbenzene ligand, two chloride ligands and a pyridylurea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is obsd. due to two strong N-H···Cl interactions between the NH groups of urea and the two chloride ligands of neighboring mols. The C=O group of the urea moiety interacts with the solvent mol. through weak C-H···O interactions. Crystallog. data and at. coordinates are given. [on SciFinder(R)] - PublicationMétadonnées seulementDichlorido[1-(2-chloro-eth-yl)-3-(pyridin-4-ylmethyl-?N)urea](?-hexa-methyl-benzene)-ruthenium(II) chloro-form monosolvate(2011)
; The Ru(II) atom in the title compound, [RuCl(2)(C(12)H(18))(C(9)H(12)ClN(3)O)]?CHCl(3), exhibits a typical piano-stool coordination, defined by a hexa-methyl-benzene ligand, two chloride ligands and a pyridyl-urea ligand coordinated through the pyridine N atom. In the crystal, a dimeric structure is observed due to two strong N-H(midline ellipsis)Cl inter-actions between the NH groups of urea and the two chloride ligands of neighbouring mol-ecules. In addition, the C=O group of the urea moiety inter-acts with the solvent mol-ecule through weak C-H(midline ellipsis)O interactions.[on SciFinder (R)] - PublicationMétadonnées seulementNew dinuclear Ru2(CO)4 sawhorse-type complexes containing bridging carboxylato ligands(2009)
; The thermal reaction of Ru3(CO)12 with ethacrynic acid, 4-[bis(2-chlorethyl)amino]benzenebutanoic acid (chlorambucil), or 4-phenylbutyric acid in refluxing solvents, followed by addn. of 2-electron donor ligands (L), gives the diruthenium complexes Ru2(CO)4(O2CR)2L2 (1: R = CH2O-C6H2Cl2-COC(CH2)C2H5, L = py; 2: R = CH2O-C6H2Cl2-COC(CH2)C2H5, L = PPh3; 3: R = C3H6-C6H4-N(C2H4-Cl)2, L = py; 4: R = C3H6-C6H4-N(C2H4-Cl)2, L = PPh3; 5: R = C3H6-C6H5, L = py; 6: R = C3H6-C6H5, L = PPh3). The single-crystal structure analyses of 2, 3, 5, and 6 reveal a dinuclear Ru2(CO)4 sawhorse structure, the diruthenium backbone being bridged by the carboxylato ligands, while the 2 L ligands occupy the axial positions of the diruthenium unit. [on SciFinder(R)] - PublicationMétadonnées seulementArene-ruthenium complexes with ferrocene-derived ligands: Synthesis and characterization of complexes of the type [Ru(?6-arene)(NC5H4CH2NHOC-C5H4FeC5H5)Cl2] and [Ru(?6-arene)(NC3H3N(CH2)2O2C-C5H4FeC5H5)Cl2](2009)
; ; - PublicationMétadonnées seulementMesomorphic Metallo-Dendrimers Based on the Metal-Metal Bonded Ru2(CO)4 Sawhorse Unit(2008)
; - PublicationMétadonnées seulementFerrocenoyl Pyridine Arene Ruthenium Complexes with Anticancer Properties: Synthesis, Structure, Electrochemistry, and Cytotoxicity(2008)
; ; - PublicationMétadonnées seulementSynthesis, structure and electrochemistry of cationic diruthenium complexes of the type [(N-N)2Ru2(CO)2(?-CO)2(?-OOCFc)]+ containing a ferrocenecarboxylato bridge and two chelating aromatic diimine ligands(2007)
; ; - PublicationMétadonnées seulementRu2(CO)4(OOCR)2(PPh3)2 sawhorse-type complexes containing ?2-?2-carboxylato ligands derived from biologically active acids(2006)
; The thermal reaction of Ru3(CO)12 with the biol. active acids acetyl salicylic acid (Aspirin), ?-methyl-4-(isobutyl)phenylacetic acid (Ibuprofen) and 3?,7?,12?-trihydroxy-5?-cholanic acid (cholic acid) in refluxing THF, followed by addn. of PPh3, gives the dinuclear complexes Ru2(CO)4(OOCR)2(PPh3)2 (1: R = C6H4-2-OCOMe, 2: R = CHMe-C6H4-4-Bui, 3: C23H39O3). The single-crystal structural anal. of 1 and 2 reveals a dinuclear Ru2(CO)4 sawhorse structure, the diruthenium backbone being bridged by the carboxylato ligands, while the two phosphine ligands occupy the axial positions at the Ru atoms. However, chiral C atoms in the carboxylic acid undergo racemization during the thermal reaction. [on SciFinder(R)] - PublicationMétadonnées seulementDinuclear ruthenium sawhorse-type complexes containing bridging ligands with ferrocenyl substituents in endo/endo, endo/exo and exo/exo orientations(2006)
; ; The dinuclear Ru complexes Ru2(CO)4(OOCC5H4FeC5H5)2L2 (L = py: 1, L = PPh3: 2) were synthesized from Ru3(CO)12, ferrocene carboxylic acid and pyridine or PPh3, resp. The single-crystal x-ray structure anal. reveals for 1 and 2 a Ru2(CO)4 sawhorse backbone with the two ferrocenyl substituents of the two carboxylato bridges being endo/exo with respect to each other in the solid state. With the new pyridine deriv. NC5H4OOCC5H4FeC5H5-4 (4-ferrocenoyloxypyridine) (3) as axial ligand, the complex Ru2(CO)4(OOCC5H4FeC5H5)2(NC5H4OOCC5H4FeC5H5-4)2 (4) was obtained, the single crystal x-ray structure anal. showing an exo/exo orientation of the two carboxylato bridges in the solid state. The endo/endo orientation is found in the solid-state structure of Ru2(CO)4(HNOCC5H4FeC5H5)2(PPh3)2 (5), the two OCNH bridges being transoid with respect to each other; this complex is accessible from Ru3(CO)12, ferrocenamide and PPh3. [on SciFinder(R)]