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Deschenaux, Robert

Nom
Deschenaux, Robert
Affiliation principale
Fonction
Professeur.e ordinaire
Email
Robert.Deschenaux@unine.ch
Identifiants
https://libra.unine.ch/handle/123456789/384
_
0000-0002-1142-0022

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Calamitic liquid crystals containing metal?metal bonds: design of mesomorphic materials based on the Ru 2 (CO) 4 (µ- 2-O 2 CR) 2 L 2 sawhorse unit

1997, Deschenaux, Robert, Donnio, Bertrand, Rheinwald, Gerd, Stauffer, Frédéric, Süss-Fink, Georg, Velker, Jörg

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Calamitic liquid crystals containing metal-metal bonds: design of mesomorphic materials based on the Ru2(CO)4(?-?2-O2CR)2L2 sawhorse unit

1997, Deschenaux, Robert, Donnio, Bertrand, Rheinwald, Gerd, Stauffer, Frederic, Süss-Fink, Georg, Velker, Jorg

Complexes based on the stable [Ru2(CO)4(?-?2-O2CR)2L2] sawhorse unit were prepd. and characterized. [Ru2(CO)4(?-?2-O2CR)2{NC5H4(CO2C6H4OCnH2n+1-p)-p}2] (R = H, n = 10; R = C6H5, n = 6, 10, 12, 14 or 16; R = C6H4CH3-p, n = 10; R = C6H4OCH3-p, n = 6, 10 or 16) proved to be mesomorphic, giving rise to nematic phases. [on SciFinder(R)]

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Calamitic liquid crystals containing metal–metal bonds : design of mesomorphic materials based on the Ru2(CO)4(µ-η2-O2CR)2L2 sawhorse unit

1997, Deschenaux, Robert, Donnio, Bertrand, Rheinwald, Gerd, Stauffer, Frédéric, Süss-Fink, Georg, Velker, Jörg

A series of complexes based on the stable [Ru2(CO)4(µ-η2-O2CR)2L2] sawhorse unit has been prepared and characterized. The derivatives [Ru2(CO)4(µ-η2-O2CR)2{NC5H4(CO2C6H4OCnH2n+1-p)-p}2] (R = H, n = 10; R = C6H5, n = 6, 10, 12, 14 or 16; R = C6H4CH3-p, n = 10; R = C6H4OCH3-p, n = 6, 10 or 16) proved to be mesomorphic, giving rise to nematic phases.

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