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Dichlorido(furfurylamine-κN)(η6-hexamethylbenzene)ruthenium(II)

2011, Garci, Amine, Thai, Trieu-Tien, Süss-Fink, Georg, Therrien, Bruno

The single-crystal X-ray structure analysis of [RuCl2(C12H18)(C5H7NO)] reveals a distorted piano-stool geometry around the RuII atom, with a hexamethylbenzene ligand, two chloride ligands and a furfurylamine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H...Cl interactions between two symmetry-related molecules.

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Métadonnées seulement

Dichlorido(furfuryl-amine-?N)(?-hexa-methyl-benzene)-ruthenium(II)

2011, Garci, Amine, Thai, Trieu-Tien, Süss-Fink, Georg, Therrien, Bruno

The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa-methyl-benzene ligand, two chloride ligands and a furfuryl-amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H(midline ellipsis)Cl inter-actions between two symmetry-related mol-ecules.[on SciFinder (R)]

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Publication
Métadonnées seulement

Dichlorido(furfurylmine-?N)(?6-hexamethylbenzene)ruthenium(II)

2011, Garci, Amine, Thai, Trieu-Tien, Süss-Fink, Georg, Therrien, Bruno

The single-crystal x-ray structure anal. of [RuCl2(C12H18)(C5H7NO)] reveals a distorted piano-stool geometry around the RuII atom, with a hexamethylbenzene ligand, two chloride ligands and a furfurylamine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is obsd. as a result of N-H···Cl interactions between two symmetry-related mols. Crystallog. data and at. coordinates are given. [on SciFinder(R)]