The cluster dication [(eta(6)-C6H6)(2)(eta(6)-C6Me6)(4)Ru-8(mu(2)-H)(2)(mu(3)-O)(2)(mu(2)-Cl) (2)](2+): a chloro-bridged framework containing two metal tetrahedra
Author(s)
Date issued
2002
In
Inorganic Chemistry Communications
Vol
1
No
5
From page
9
To page
11
Subjects
cluster octanuclear terahedral ruthenium arene ligand oxo cap AQUEOUS-SOLUTION TRINUCLEAR BUILDUP
Abstract
The title complex was obtained by reacting [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(2)-H)(3)(mu(3)-O)(+) with RuCl3 . nH(2)O in aqueous solution. it crystallises as the tetrafluoroborate salt. The cationic cluster is formed of two tetrahedral Ru-4 substructures which are held together by two chloro bridges. (C) 2002 Elsevier Science B.V. All rights reserved.
Publication type
journal article