Di-mu-acetato-kappa O-4 : O '-tetracarbonylbis(pyridyl-2-yl-kappa N-amine)diruthenium(I)(Ru-Ru)
Author(s)
Date issued
2004
In
Acta Crystallographica Section E-Structure Reports Online
No
60
From page
M1397
To page
M1399
Subjects
COMPLEXES
Abstract
The structure of the title compound, [Ru-2(C2H3O2)(2)(C5H6N2)(2)(CO)(4)], consists of a 'sawhorse' diruthenium complex with two acetate bridges and two 2-aminopyridine ligands in the axial positions, coordinating via the pyridine N atoms. A double-stranded hydrogen-bonded chain is formed via intra- and intermolecular hydrogen bonds involving the amine groups, one O atom of both acetate groups and two carbonyl O atoms.
Publication type
journal article