Dichloro(?6-p-cymene)[?1-(2,4,6-tri-tert-butylphenyl)phosphine-?P]osmium(II)
Author(s)
Burrell, Anthony K.
Date issued
2004
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
6
No
60
From page
m863
To page
m864
Subjects
osmium chloro cymene butylphenylphosphine prepn crystal structure mol structure osmium chloro cymene butylphenylphosphine
Abstract
Crystals of the title compd. are monoclinic, space group C2/c, with a 15.3347(2), b 13.0280(2), c 31.6125(4) Å, ? 102.678(1)°; Z = 8, dc = 1.453; R = 0.031, Rw(F2) = 0.081 for 6510 reflections. The presence of bulky substituents imposes a structural distortion on the (2,4,6-tri-tert-butylphenyl)phosphine ligand, which is bowed. [on SciFinder(R)]
Publication type
journal article