Cationic dinuclear arene ruthenium complexes with one hydroxo and two chloro bridges: synthesis and molecular structure of [(p-Me-C6H4 Pr-i)(2)Ru-2(mu-Cl)(2)(mu-OH)][ReO4]
Author(s)
Fidalgo, Eva Garcia
Plasseraud, Laurent
Date issued
2001
In
Inorganic Chemistry Communications
Vol
6
No
4
From page
308
To page
310
Subjects
OSMIUM COMPLEXES AQUEOUS-SOLUTION X-RAY LIGANDS TETRANUCLEAR ACTIVATION BINUCLEAR
Abstract
The dinuclear complexes (arene)(2)Ru2Cl4 (arene = benzene, p-cymene, durene, hexamethylbenzene) react in aqueous solution to give, in addition to the known cationic trichloro complexes [(arene)(2)Ru-2(mu -Cl)(3)](+), the new dichloro hydroxo cations [(arene)(2)Ru-2(mu -Cl)(2)(mu -OH)](+) which can be isolated as the perrhenate salts. (C) 2001 Published by Elsevier Science B.V.
Publication type
journal article