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  4. [Bis(2-pyridyl-?N)amine]chlorido(?6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate

[Bis(2-pyridyl-?N)amine]chlorido(?6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate

Author(s)
Gupta, Gajendra
Therrien, Bruno  
Institut de chimie  
Kim, Jinkwon
Date issued
2011
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
5
No
67
Subjects
mol structure ruthenium pyridylamine chlorido hexamethylbenzene hexafluoridophosphate dichloromethane solvate crystal structure ruthenium pyridylamine chlorido hexamethylbenzene hexafluoridophosphate dichloromethane solvate hydrogen bond ruthenium pyridylamine chlorido hexamethylbenzene hexafluoridophosphate dichloromethane solvate
Abstract
In the title half-sandwich complex, [RuCl(?6-C12H18)(C10H9N3)]PF6·CH2Cl2, the Ru(II) ion is four-coordinated by a chloro, a hexamethylbenzene and a bidentate N,N'-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N-H group forms a H bond with the chloro ligand of a neighboring complex, thus forming chains along the b axis. Weak intermol. C-H...F and C-H. Cl contacts are also obsd. Crystallog. data and at. coordinates are given. [on SciFinder(R)]
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/51899
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