Bis[dichloro-?6-indaneruthenium(II)] chloroform solvate
Author(s)
Date issued
2002
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
11
No
58
From page
m656
To page
m657
Subjects
ruthenium chloro indane chloroform prepn crystal structure mol structure ruthenium chloro indane chloroform
Abstract
The title compd. was prepd. from RuCl3.3H2O and bicyclo[4.3.0]nona-3,6(1)-diene and its crystal structure detd. Crystals of the compd. are monoclinic, space group P21/c, with a 10.5187(10), b 11.6680(15), c 11.4020(10) Å, ? 99.793(11)°; Z = 4, dc = 1.972; R = 0.032, Rw(F2) = 0.089 for 2528 reflections. The indane ligands adopt an envelope conformation toward the Ru atoms. The dimeric chloro-bridged mol. has crystallog. inversion symmetry. [on SciFinder(R)]
Publication type
journal article