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  4. rac-Ethyl 2-bromo-2-[(3R,5R)-3-bromo-5-methyltetrahydrofuran-2-ylidene]acetate

<i>rac</i>-Ethyl 2-bromo-2-[(3<i>R</i>,5<i>R</i>)-3-bromo-5-methyltetrahydrofuran-2-ylidene]acetate

Author(s)
Loiseau, François
Neier, Reinhard  
Institut de chimie  
Labat, Gael
Stoeckli-Evans, Helen  
Institut de chimie  
Date issued
2006
In
Acta Crystallographica Section C, Blackwell, 2006/62/11/o636-o638
Abstract
In the title compound, C<sub>9</sub>H<sub>12</sub>Br<sub>2</sub>O<sub>3</sub>, a (tetrahydrofuran-2-ylidene)acetate, the double bond has the Z form. In the tetrahydrofuran group, the relative configuration of the Br atom in the 3-position and the methyl group in the 5-position is <i>anti</i>. The compound crystallizes with two independent molecules per asymmetric unit and, in the crystal structure, the individual molecules are linked to their symmetry-equivalent molecules by C***HO hydrogen bonds, so forming centrosymmetric hydrogen-bonded dimers.
Publication type
journal article
Identifiers
https://libra.unine.ch/handle/20.500.14713/58044
DOI
10.1107/S0108270106037127
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Loiseau_Fran_ois_-_rac-_Z_-Ethyl2-bromo-2_20070706.pdf

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