[RuCl{2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine}(PPh3)2]BF4 dichloromethane solvate
Author(s)
Date issued
2002
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
10
No
58
From page
m557
To page
m558
Subjects
crystal structure ruthenium chloro pyrrolylpyridine phenylphosphine fluoroborate chloromethane mol structure ruthenium chloro pyrrolylpyridine phenylphosphine fluoroborate
Abstract
The tetrafluoroborate salt of the mononuclear octahedral Ru(II) complex, [RuCl(L)(PPh3)2]BF4, where L = 2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine, was prepd. as the CH2Cl2 solvate. Crystals are triclinic, space group P?1, with a 10.3368(8), b 12.7939(11), c 19.1336(16) Å, ? 80.231(10), ? 89.193(9), ? 67.943(9)°; Z = 2, dc = 1.505; R = 0.031, Rw(F2) = 0.076 for 8322 reflections. The PPh3 ligands adopt a trans configuration, with a P-Ru-P angle of 173.72(2)°. [on SciFinder(R)]
Publication type
journal article