[?6-2-(2-Methylbenzoyloxy)ethyl methacrylate]bis(?6-1,2,4,5-tetramethylbenzene)tri-?-hydrido-?3-oxo-triruthenium(II)(3 Ru-Ru) tetrafluoroborate
Author(s)
Vieille-Petit, Ludovic
Buryak, Andrey
Severin, Kay
Date issued
2004
In
Acta Crystallogr., Sect. E: Struct. Rep. Online
Vol
12
No
60
From page
m1909
To page
m1911
Subjects
ruthenium methylbenzoyloxyethyl methacrylate methylbenzene hydro oxo fluoroborate prepn structure crystal structure ruthenium methylbenzoyloxyethyl methacrylate methylbenzene hydro oxo fluoroborate mol structure ruthenium methylbenzoyloxyethyl methacrylate methylbenzene hydro oxo fluoroborate
Abstract
The trinuclear arene-Ru cluster cation, [Ru3H3(O)(C10H14)2(C14H16O4)]+, was synthesized and crystd. as the tetrafluoroborate (BF4-) salt. Crystals of the salt are monoclinic, space group P21/c, with a 13.592(3), b 17.817(4), c 15.066(4) Å, ? 100.238(3)°; Z = 4, dc = 1.713; R = 0.039, Rw(F2) = 0.087 for 8673 reflections. The cations form, along the b axis, infinite 1-dimensional chains through ?-stacking interactions. [on SciFinder(R)]
Publication type
journal article