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Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands: Synthesis and structure of [Ru-3(CO)(9)(PCy3)(3)] and [Ru3H2(CO)(6)(PCy3)(3)]
Auteur(s)
Godefroy, Isabelle
Ferrand, Vincent
Neels, Antonia
Date de parution
1998
In
Journal of the Chemical Society-Dalton Transactions
Vol.
4
De la page
515
A la page
516
Résumé
The reaction of Na[Ru3H(CO)(11)] with an excess of tricyclohexylphosphine in methanol afforded, depending on the reaction conditions, the tri-substituted clusters [Ru-3(CO)(9)(PCy3)(3)] (48e) and [Ru3H2(CO)(6)(PCy3)(3)] (44e), inaccessible hitherto.
Type de publication
Resource Types::text::journal::journal article
