Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands: Synthesis and structure of [Ru-3(CO)(9)(PCy3)(3)] and [Ru3H2(CO)(6)(PCy3)(3)]
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Journal of the Chemical Society-Dalton Transactions
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The reaction of Na[Ru3H(CO)(11)] with an excess of tricyclohexylphosphine in methanol afforded, depending on the reaction conditions, the tri-substituted clusters [Ru-3(CO)(9)(PCy3)(3)] (48e) and [Ru3H2(CO)(6)(PCy3)(3)] (44e), inaccessible hitherto.
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Resource Types::text::journal::journal article