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Rhodium(I) iminophosphine poly(propyleneimine) dendrimers: Synthesis, characterization and molecular structure of a mononuclear analogue

Auteur(s)
Antonels, Nathan C.
Moss, John R.
Smith, Gregory S.
Date de parution
2009
In
Inorg. Chem. Commun.
Vol.
8
No
12
De la page
716
A la page
719
Mots-clés
Résumé
First (G1)- and second-generation (G2) poly(propyleneimine) (PPI) dendrimers were reacted with 2-(diphenylphosphino)benzaldehyde, to form iminophosphine-functionalized dendritic ligands (1, 2). The reaction of the dimeric precursor [RhCl(CO)2]2 with the heterobidentate dendritic ligands 1, 2 gave the corresponding rhodium(I) complexes (3, 4). [on SciFinder(R)]
URI
Type de publication
Resource Types::text::journal::journal article